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| | ONLINE | ISSN | : | 1348-0634 | | PRINT | ISSN | : | 0009-2673 |
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| | Bulletin of the Chemical Society of Japan |
| Vol. 72 (1999) , No. 1 pp.33-36 |
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 | Formation of a Trinuclear Mercury(II) Complex Mediated by a Phosphorane: Molecular Structure of [Hg{Hg(I)(Ph3PCHCOPh)(μ-I)2}2]
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| | 1) Department of Chemistry, Bharathidasan University
2) Department of Physics, Bharathidasan University
3) Department of Chemistry, University of Canterbury |
| (Received March 30, 1998)
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Phenacylidenetriphenylphosphorane reacts with HgI2 in 2 : 3 molar ratio to form a novel trinuclear iodobridged symmetrical complex whose structure has been elucidated by IR, multinuclear NMR, and X-ray crystallography. The Hg···Hg distance [3.648(1) Å] indicates a negligible bonding interaction between the mercury atoms. |
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| doi:10.1246/bcsj.72.33 | | JOI JST.JSTAGE/bcsj/72.33 |
| Copyright (c) 2003 The Chemical Society of Japan |
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