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ONLINEISSN:1348-0634
PRINTISSN:0009-2673
Bulletin of the Chemical Society of Japan
Vol. 78 (2005) , No. 7 pp.1256-1258
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On Infrared Intensities of Spinel, MgAl2O4
Isao Kanesaka1), Yuichi Hayashi1) and Yoshiyuki Morioka2)
1) Faculty of Science, Toyama University
2) Faculty of Science, Saitama University
(Received November 29, 2004)

In spinel (MgAl2O4), the strongest infrared band at 485 cm−1 shows less LO–TO splitting than the medium band at 670 cm−1. This unexpected relationship is explained in terms of the vibrational coupling of these TO modes. A new manner for evaluating the LO mode is proposed.

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doi:10.1246/bcsj.78.1256
JOI  JST.JSTAGE/bcsj/78.1256
Copyright (c) 2005 The Chemical Society of Japan



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