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ONLINEISSN:1348-0634
PRINTISSN:0009-2673
Bulletin of the Chemical Society of Japan
Vol. 78 (2005) , No. 7 pp.1283-1284
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A Solvothermal Synthesis and the Structure of (NH4)2Ag6Sn3S10
Menghe BaiYin1), Ling Ye2), Yonglin An1), Xin Liu1), Cuiying Jia1) and Guiling Ning1)
1) Department of Chemistry, Dalian University of Technology
2) Key Laboratory for Supramolecular Structure and Materials of the Ministry of Education on Jilin University
(Received July 16, 2004)

A novel framework, (NH4)2Ag6Sn3S10, was synthesized solvothermally and characterized by single-crystal X-ray diffraction. The framework comprises silver-rich cationic layers, [Ag6SnS4]2+, pillared by [SnS3]2− zigzag chains formed by vertex-sharing SnS4 tetrahedra; NH4+ ions are located in 1D channels.

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doi:10.1246/bcsj.78.1283
JOI  JST.JSTAGE/bcsj/78.1283
Copyright (c) 2005 The Chemical Society of Japan



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