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ONLINEISSN:1348-0634
PRINTISSN:0009-2673
Bulletin of the Chemical Society of Japan
Vol. 78 (2005) , No. 7 pp.1285-1287
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Zn(II) Complexes with Aliphatic Thiolates. (Et4N)[Zn(SAd)3] and (Et4N)2[{Zn(ScHex)2}2(μ-ScHex)2]
Yuki Matsunaga1), Kiyoshi Fujisawa1), Naoko Ibi1), Nagina Amir1), Yoshitaro Miyashita1) and Ken-ichi Okamoto1)
1) Graduate School of Pure and Applied Sciences, University of Tsukuba
(Received February 7, 2005)

New homoleptic aliphatic thiolato complexes with Zn(II), (Et4N)[Zn(SAd)3] (1) (HSAd = 1-adamantanethiol), and (Et4N)2[{Zn(ScHex)2}2(μ-ScHex)2] (2) (HScHex = 1-cyclohexanethiol), have a novel three-coordinate geometry for monomeric 1 and a tetrahedral geometry for dimeric 2, respectively. The complexes have been fully characterized by far-IR, Raman, and UV–vis absorption spectroscopy.

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doi:10.1246/bcsj.78.1285
JOI  JST.JSTAGE/bcsj/78.1285
Copyright (c) 2005 The Chemical Society of Japan



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