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ONLINEISSN:1348-0634
PRINTISSN:0009-2673
Bulletin of the Chemical Society of Japan
Vol. 78 (2005) , No. 7 pp.1288-1290
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Dinuclear Pt(II) and Pd(I) Complexes with Bridging PPh2 Ligands from the Reaction of PPh2H with Zero-Valent Complexes of These Metals
Makoto Tanabe1), Masumi Itazaki1), Osamu Kitami1), Yasushi Nishihara1) and Kohtaro Osakada1)
1) Chemical Resources Laboratory (Mail Box R1-3), Tokyo Institute of Technology
(Received February 23, 2005)

Reactions of PPh2H with [M(PCy3)2] (M = Pt, Pd) produce the dinuclear complexes with bridging PPh2 ligands of these metals, [{Pt(H)(PCy3)}2(μ-PPh2)2] and [{Pd(PCy3)}2(μ-PPh2)2], respectively.

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doi:10.1246/bcsj.78.1288
JOI  JST.JSTAGE/bcsj/78.1288
Copyright (c) 2005 The Chemical Society of Japan



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