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ONLINEISSN:1348-0634
PRINTISSN:0009-2673
Bulletin of the Chemical Society of Japan
Vol. 78 (2005) , No. 7 pp.1371-1372
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Specific Acceleration of the Hydrogenation of Methyl Acetoacetate on Enantio-Differentiating Sites of a Tartaric Acid-Modified Nickel Catalyst by the Addition of Acetic Acid to the Reaction Media
Tsutomu Osawa1), Masashi Ando1), Tadao Harada2) and Osamu Takayasu1)
1) Faculty of Science, Toyama University
2) Faculty of Science and Technology, Ryukoku University
(Received January 25, 2005)

The hydrogenation of methyl acetoacetate on enantio-differentiating sites of a tartaric acid-modified nickel catalyst was specifically accelerated by the addition of acetic acid to the reaction media to increase the enantio-differentiating ability of the catalyst.

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doi:10.1246/bcsj.78.1371
JOI  JST.JSTAGE/bcsj/78.1371
Copyright (c) 2005 The Chemical Society of Japan



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