 | Versatile Vapochromic Behavior Accompanied by a Phase Change between Charge-Polarization State and Charge-Density-Wave State in a Quasi-One-Dimensional Iodo-Bridged Dinuclear Platinum Mixed-Valence Compound, [{NH3(CH2)5NH3}2][Pt2(pop)4I]·4H2O
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| | Masahiro Yamashita1)4), Kouichi Takizawa2), Satoshi Matsunaga2), Daisuke Kawakami1)4), Hiroaki Iguchi1)4), Shinya Takaishi1)4), Takashi Kajiwara1)4), Fumiyasu Iwahori2), Tomohiko Ishii2), Hitoshi Miyasaka2), Ken-ichi Sugiura2), Hiroyuki Matsuzaki3), Hideo Kishida3) and Hiroshi Okamoto3) |
| 1) Department of Chemistry, Graduate School of Science, Tohoku University
2) Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University
3) Department of Advanced Materials Science, Graduate School of Frontier Science, The University of Tokyo
4) CREST (JST) |
| (Received February 15, 2006)
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This communication describes versatile vapochromic behavior that is accompanied by a phase change between charge-polarization (CP) and charge-density-wave (CDW) states with increasing and decreasing temperature in [{NH3(CH2)5NH3}2][Pt2(pop)4I]·4H2O (pop = P2H2O52−) (1). |
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