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ONLINEISSN:1348-0715
PRINTISSN:0366-7022
Chemistry Letters
Vol. 26 (1997) , No. 9 p.951
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Chiral Bis(oxazolinyl)phenyl Rhodium and Palladium Complexes
Yukihiro Motoyama1), Nobuyuki Makihara1), Yoshiharu Mikami1), Katsuyuki Aoki1) and Hisao Nishiyama1)
1) School of Materials Science, Toyohashi University of Technology
(Received June 10, 1997)

The transmetalation of Phebox-ip-SnMe3 [Phebox = 2,6-bis(oxazolinyl)phenyl] 1c with RhCl3(H2O)3 and PdCl2(PhCN)2 gave (Phebox-ip)RhCl2(H2O) 2a and (Phebox-ip)PdCl 3 under mild conditions in 45% and 96% yields, respectively. The crystal structures of (Phebox-ip)RhCl2(t-BuNC) 2b, which was obtained by the reaction of 2a with t-BuNC, and 3 have been determined by X-ray diffraction.

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doi:10.1246/cl.1997.951
JOI  JST.JSTAGE/cl/1997.951
Copyright (c) 2004 The Chemical Society of Japan



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