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| Effect of Cyclen on the Prolongation of M Intermediate Lifetime in the D96N Mutant of Bacteriorhodopsin
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| | | 1) Laboratory of Colloid and Interface, Center of Molecular Science, Institute of Chemistry the Chinese Academy of Sciences |
| (Received January 17, 2002)
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| A new kind of chemical additive—cyclen (1,4,7,10-tetra-azacyclododecane) was used in BRD96N-PVA films in an attempt to obtain longer M state lifetime. At the highest cyclen concentration of 1:250, the lifetime of M state could be prolonged to 936 s. Comparing the lifetimes of the M state in BRD96N suspension and BRD96N-PVA film with the same cyclen content, it is the strong complexing properties of cyclen towards H+ that plays the most important role in this prolongation. | | | | |  | Please click this button non-subscribers to purchase a paper individually. |
 | doi:10.1246/cl.2002.558 |  | JOI JST.JSTAGE/cl/2002.558 | | Copyright (c) 2002 The Chemical Society of Japan |
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