CL : Vol. 34 (2005) , No. 8 p.1180

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Chemistry Letters

Vol. 34 (2005) , No. 8 p.1180

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Synthesis of Novel Dendritic α-Glycol Ligands Derived from DL-Dithiothreitol and Their Application to Ring-opening Polymerization of ε-Caprolactone

Ken-ichi Fujita¹⁾, Takahito Muraki¹⁾, Takayuki Sakurai¹⁾, Akihiro Oishi¹⁾ and Yoichi Taguchi¹⁾

1) National Institute of Advanced Industrial Science and Technology (AIST)

(Received June 24, 2005)

A series of dendritic ligands with an α-glycol core was synthesized through the coupling of DL-dithiothreitol with poly(arylether) dendron in high yields. The corresponding aluminum dendrimers were applied as initiator to ring-opening polymerization of ε-caprolactone. A dendritic effect on the polydispersity (M_w/M_n) of poly(ε-caprolactone) was observed.

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	doi:10.1246/cl.2005.1180
	JOI JST.JSTAGE/cl/2005.1180

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