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 | Structures and Sorption Properties of Ionic Crystals of Polyoxometalates with Macrocation
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| | 1) Department of Applied Chemistry, School of Engineering, The University of Tokyo
2) Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency |
| (Received February 15, 2006)
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Polyoxometalates are nanosized metal–oxygen macroanions and suitable building blocks of ionic crystals with nanostructures in combination with appropriate macrocations. In this review, (1) formation of ionic crystals by the complexation of the polyoxometalates with a macrocation and the hydrophilic guest sorption properties, (2) effects of charges of polyoxometalates on the structures and sorption properties of ionic crystals, and (3) construction of both hydrophilic and hydrophobic channels in the crystal lattice of the polyoxometalate based ionic crystals are highlighted. |
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| doi:10.1246/cl.2006.688 | | JOI JST.JSTAGE/cl/2006.688 |
| Copyright (c) 2006 The Chemical Society of Japan |
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