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ONLINEISSN:1348-0715
PRINTISSN:0366-7022
Chemistry Letters
Vol. 36 (2007) , No. 7 p.830
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Rhodium-catalyzed Selective Cross-coupling of Internal Alkynes with a Terminal Silylacetylene
Takashi Katagiri1), Hayato Tsurugi1), Atsushi Funayama1), Tetsuya Satoh1) and Masahiro Miura1)
1) Department of Applied Chemistry, Faculty of Engineering, Osaka University
(Received April 11, 2007)

The cross-coupling of a number of internal arylalkynes with a representative terminal alkyne, tert-butyldimethylsilylacetylene, proceeds regio- and stereoselectively in the presence of a rhodium catalyst to produce the corresponding enyne compounds with good yield.

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doi:10.1246/cl.2007.830
JOI  JST.JSTAGE/cl/2007.830
Copyright (c) 2007 The Chemical Society of Japan



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