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 | Metal Ion-coupled Electron-transfer Reduction of Dioxygen
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| | 1) Department of Material and Life Science, Graduate School of Engineering, Osaka University
2) SORST, Japan Science and Technology Agency |
| (Received April 11, 2008)
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Metal ion-coupled and proton-coupled electron-transfer reactions of dioxygen is described for one-electron, two-electron, and four-electron reduction of dioxygen by one-electron reductants such as ferrocene derivatives as well as by two-electron reductants such as NADH analogs. The catalytic mechanism of the four-electron reduction of dioxygen with cofacial dicobalt porphyrins has been clarified based on the detailed kinetic study and the detection of the intermediate. |
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| doi:10.1246/cl.2008.808 | | JOI JST.JSTAGE/cl/2008.808 |
| Copyright (c) 2008 The Chemical Society of Japan |
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