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ONLINEISSN:1348-0715
PRINTISSN:0366-7022
Chemistry Letters
Vol. 38 (2009) , No. 6 p.546
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External Electric Field Effects on Emission of a Dendrimer-encapsulated Gold Nanocluster in a Polymer Film
Ruriko Ohshima1)2), Takakazu Nakabayashi1)2), Tatsuo Hamada1) and Nobuhiro Ohta1)2)
1) Research Institute for Electronic Science (RIES), Hokkaido University
2) Graduate School of Environmental Science, Hokkaido University
(Received March 6, 2009)

External electric field effects on emission spectrum of a dendrimer-encapsulated gold cluster in a PVA film have been examined with electric field modulation spectroscopy. Besides the Stark shift, a field-induced quenching of the emission is observed, indicating the field-induced enhancement of the rates of nonradiative processes from the emitting state.

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doi:10.1246/cl.2009.546
JOI  JST.JSTAGE/cl/2009.546
Copyright (c) 2009 The Chemical Society of Japan

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