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Chemistry Letters
Vol. 39 (2010) , No. 2 p.78
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The Diversified Reactivities of 1,5-Bisallenes
Guofei Chen1), Xuefeng Jiang2), Chunling Fu1) and Shengming Ma1)2)
1) Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University
2) State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
(Received October 16, 2009)

1,5-Bisallenes may undergo radical, carbometallation, cyclometallation, cyclization, and consecutive cascade reactions to form many different 5–7-membered rings, showing diversified reactivities. There is no doubt that the chemistry of 1,5-bisallenes would be enriched by further study.

 

 


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doi:10.1246/cl.2010.78
JOI  JST.JSTAGE/cl/2010.78
Copyright (c) 2010 The Chemical Society of Japan



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