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ONLINEISSN:1348-0715
PRINTISSN:0366-7022
Chemistry Letters
Vol. 39 (2010) , No. 3 p.148
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Carotenoid Radicals: Cryptochemistry of Natural Colorants
Lowell D. Kispert1) and Nikolay E. Polyakov2)
1) Chemistry Department, University of Alabama
2) Institute of Chemical Kinetics and Combustion
(Received October 23, 2009)

This review examines the properties and uses of carotenoid radicals. Their mechanisms of action on the molecular level play a crucial role in electron transfer and light regulation processes in photosynthesis, in the design of improved artificial solar cells, and in the scavenging of toxic free radicals. There is a remarkable increase in the quantum yield and the lifetime of the charge-separated states of the carotenoid radical cations in the supramolecular “hosts” β-glycyrrhizic acid (GA) and arabinogalactan (AG).

 

 


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doi:10.1246/cl.2010.148
JOI  JST.JSTAGE/cl/2010.148
Copyright (c) 2010 The Chemical Society of Japan



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