A concept of chemical potential pumping effect was introduced to describe the NO
x sensing mechanism of oxide catalysts with high electronic conductivity and large carrier density. When NO
x gas in a gas-stream decomposed on the surface of the catalyst oxides continuously, the high oxygen potential released by the decomposition of NO
x stationarily covered the whole surface of the oxide. Then, the bulk oxide was equilibrated with the steady-state high oxygen potential of the surface, which was much larger than that determined by the oxygen pressure of the surrounding gas-phase. This effect was confirmed by the conductivity enhancement of La
2CuO
4 and La
0.5Sr
0.5FeO
3 with NO
2 as well as nonstoichiometry variation of La
0.5Sr
0.5CoO
3 and EMF of galvanic cell with La
0.6Sr
0.4CoO
3−d. It was shown that the chemical potential pumping effect appears essentially on dense materials while the effect is hardly observed on porous material with large surface relative. On La
0.5Sr
0.5FeO
3 as well as on La
2CuO
4, NO
2 was found to decompose into NO and O
2, while NO was almost inactive on these oxides.
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