In order to find a new type of oxide ion conductor, the electrical conduction was measured in the substituted perovskite-type oxides. In the present case, LaYO
3 was used as a based material with an orthorhombic and comparatively large unit cell, and a novel substitution method was introduced to intend to increase the concentration of oxide ions,
e.g., LaY
1−xZr
xO
3+x/2. As a result, the LaYO
3-based perovskite-type solid solution was found to be formed, where the enhanced oxide ion conduction was observed as compared with that of the based material. A typical sample was LaY
0.95Zr
0.05O
3.025, the ionic conduction of which was 1.2×10
−2 S cm
−1 at 1000°C. Another substitution method of La
1−xZr
xYO
3+x/2 resulted in the analogous result. Considering these results and the further structural and density measurements, the charge carriers in these phases were expected to be due to interstitial oxide ions.
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