岩石鉱物科学
Online ISSN : 1349-7979
Print ISSN : 1345-630X
ISSN-L : 1345-630X
原著論文
福島県石川山花崗岩ペグマタイト産鉄コルンブ石の化学組成
龍 徹木股 三善西田 憲正興野 純清水 雅浩
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2005 年 34 巻 5 号 p. 242-251

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Chemical evolution of ferrocolumbites from the Ishikawa-yama granitic pegmatites, Fukushima, Japan, has been revealed by electron microprobe analysis. The compositions of ferrocolumbites are different among sample locations, which are within about 1 km distant from each other. Three discernible trends in compositional variations in ferrocolumbites have been observed: (1) a homogeneous crystal trend, with low Ta/(Ta + Nb); (2) a trend with oscillatory zoning related to Ta and Nb; (3) a trend with patchy zoning related to Fe and Mn. Oscillatory zoning of ferrocolumbite is intimately related to crystal growth in magmatic process. Ferrocolumbite with patchy zoning shows parallel extinction and doesn’t appear to have the complementary distribution of octahedral cations due to some coupled substitutions on the plots of partition coefficient (each zone/the assumed average) against ionic radius. These facts and the curved boundaries of patchy zoning suggest that patchy zoning of ferrocolumbite has been produced by topotaxy in the open system.

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© 2005 日本鉱物科学会
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