Catalytic asymmetric epoxidation is one of the most important methods to synthesize chiral building blocks. However, catalytic reactions directed by a remote functional group, several bonds distal to the reactive site of the substrates, are rare. Here, I review the asymmetric epoxidation of homo- or bishomoallylic alcohols by using metal-BHA ligand systems and regioselective epoxidation for polyene compounds by using peptide catalysts.