有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
総説および総合論文
Iron-Catalyzed C-H Bond Activation
Laurean Ilies
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2017 年 75 巻 8 号 p. 802-809

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Despite the economic and environmental merits of iron, organoiron species is largely underused for catalysis, mainly because of the difficulty in controlling its reactivity. In this account, I describe our efforts toward controlling the reactivity of transient organoiron species and its utilization for catalytic C-H bond activation. The design of an organoiron species stabilized by a bidentate directing group and a diphosphine ligand, its applications to the catalytic reaction of carboxamides with organometallic reagents or with electrophiles, and a recent iron catalyst stabilized by a triphosphine ligand capable of activating the C-H bond of weakly coordinating carbonyl compounds are described.

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© 2017 社団法人 有機合成化学協会
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