Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Structures of the Metabolites from Steviol Methyl Ester by Gibberella fujikuroi
Yoshio SHIGEMATSUNoboru MUROFUSHINobutaka TAKAHASHI
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JOURNAL FREE ACCESS

1982 Volume 46 Issue 9 Pages 2313-2318

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Abstract

Steviol methyl ester (methyl ent-13-hydroxykaur-16-en-19-oate)* was converted into five new metabolites together with a known compound, methyl ent-7α, 13-dihydroxykaur-16-en-19-oate, by Gibberella fujikuroi in the presence of a plant growth retardant. The structures of these new metabolites were elucidated to be methyl ent-7β, 13-dihydroxykaur-16-en-19-oate, methyl ent-11α, 13-dihydroxykaur-16-en-19-oate, methyl ent-7β, 11α, 13-trihydroxykaur-16-en-19-oate, methyl ent-11α, 13, 15β-trihydroxykaur-16-en-19-oate and methyl ent-13, 15β-dihydroxy-11-oxokaur-16-en-19-oate mainly by spectroscopic analyses.

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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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