JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
CORRELATION OF VAPOR-LIQUID EQUILIBRIUM DATA USING GRADUAL NONIDEALITY CONTRIBUTION RATIO
RUITEN OUYANG
Author information
JOURNAL FREE ACCESS

1970 Volume 3 Issue 2 Pages 129-137

Details
Abstract

In the prediction of the vapor composition in vapor-liquid equilibrium of the binary system A-B, using boiling points or total pressures as the only equilibrium data, as the concentration of A increases, the nonideality contribution of A changes, not suddenly but gradually, from total, 16/17, 6/7, 4/5, 3/4, 2/3, 1/2... to zero. In addition to the gradual nonideality contribution, by suitable addition of ΔXint to Xint and changing the distribution of the nonideality contribution with the addition, the prediction of vapor composition for systems in which the vapor pressure ratio (PA/PB is much greater than two has become possible. Some forty-two binary systems consisting of Hydrocarbon-Hydrocarbon, Alcohol-Water, Hydrocarbon-Alcohol, and other miscellaneous combinations have been studied and an improved, concise prediction method is illustrated.

Content from these authors
© The Society of Chemical Engineers, Japan
Next article
feedback
Top