Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Application of Liquid-Phase Microextraction and Gas Chromatography-Mass Spectrometry for the Determination of Chloroform in Drinking Water
Ru-song ZHAOChuan-ge CHENGJin-peng YUANTing JIANGLei LIXiao-bai XU
Author information
JOURNALS FREE ACCESS

2006 Volume 22 Issue 4 Pages 563-566

Details
Abstract

In this paper, a novel method for the determination of chloroform in drinking water has been described. It is based on liquid-phase microextraction (LPME) and gas chromatography-mass spectrometry (GC-MS). Extraction conditions such as solvent selection, organic solvent dropsize, stirring rate, content of NaCl and extraction time were found to have significant influence on extraction efficiency. The optimized conditions were 1.5 µl xylene, 20 min extraction time at 400 rpm stirring rate without NaCl addition. The linear range was 1.0 - 100 µg l-1 for chloroform. The limit of detection (LOD) was 1.0 µg l-1; and relative standard deviation (RSD) at the 30 µg l-1 level was 2.9%. Tap water samples from a laboratory were successfully analyzed using the proposed method. The relative recovery of spiked water samples was 104%.

Information related to the author
© 2006 by The Japan Society for Analytical Chemistry
Previous article Next article
feedback
Top