Flow-through Type Chloride Ion Selective Optodes Based on Lipophilic Organometallic Chloride Adducts and a Lipophilic Anionic Dye

Hideaki HISAMOTO; Kazuhiko WATANABE; Hitoshi OKA; Eriko NAKAGAWA; Ursula E. SPICHIGER; Koji SUZUKI

doi:10.2116/analsci.10.615

Hideaki HISAMOTO, Kazuhiko WATANABE, Hitoshi OKA, Eriko NAKAGAWA, Ursula E. SPICHIGER, Koji SUZUKI

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Keywords: Chloride ion, ion selective optode, lipophilic anionic dye, optical chemical ion sensor, organometallic compound

JOURNAL FREE ACCESS

1994 Volume 10 Issue 4 Pages 615-622

DOI https://doi.org/10.2116/analsci.10.615

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Published: August 10, 1994 Received: February 21, 1994 Available on J-STAGE: July 04, 2006 Accepted: April 13, 1994 Advance online publication: - Revised: -
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Date of correction: July 04, 2006 Reason for correction: - Correction: CITATION Details: Wrong : 1). O. S. Wolfbeis and B. P. H. Schaffer, Anal. Chim. Acta, 198, 1 (1987).
2). K. Suzuki, H. Ohzora, K. Tohda, K. Miyazaki, K. Watanabe, H. Inoue and T. Shirai, _{Anal. Chim. Acta, 237, 155 (1990).
3). K. Suzuki, K. Tohda, Y. Tanda, H. Ohzora, S. Nishihama, H. Inoue and T. Shirai, Anal. Chem., 61, 382 (1989).
4). W. E. Morf, K. Seiler, B. Rusterholz and W. Simon, Anal. Chem., 62, 738 (1990).
5). K. Seiler, W. E. Morf, B. Rusterholz and W. Simon, Anal. Sci., 5, 57 (1990).
6). S. S. S. Tan, P. C. Hauser, N. A. Chaniotakis, G. Suter and W. Simon, Chimia, 43, 257 (1989).
7). K. Miyazaki, K. Tohda, H. Ohzora, K. Watanabe, H. Inoue and K. Suzuki, Bunseki Kagaku, 39, 717 (1990).
8). H. Oka, K. Miyazaki, K. Watanabe, K. Tohda, H. Inoue and K. Suzuki, The 6lst Ann. Cong, of Chem. Soc. of Jpn., Abst., p. 650, March, 1991.
9). S. S. S. Tan, P. C. Hauser, K. Wang, K. Fluri, K. Seiler, B. Rusterholz, G. Suter, M. Kruttli, U. E. Spichiger and W. Simon, Anal. Chim. Acta, 255, 35 (1991).
10). M. A. Arnold, Anal. Chem., 64, 1015A (1992).
11). J. Janata, Anal. Chem., 64, 196R (1992).
12). J. Janata, Anal. Chem., 64, 921A (1992).
13). D. Ammann, M. Huser, B. Krautler, B. Rusterholz, P. Schulthess. B. Lindemann, E. Halder and W. Simon, Helv. Chim. Acta, 69, 849 (1986).
14). N. A. Chaniotakis, S. B. Park and M. E. Meyerhoff, Anal. Chem., 61, 566 (1989).
15). Y. Umezawa, M. Kataoka, W. Takami, E. Kimura, T. Koike and H. Nada, Anal. Chem., 60, 2392 (1988).
16). S. A. Glazier and M. A. Arnold, Anal. Chem., 63, 754 (1991).
17). P. Kubelka and Z. Munk, Z. Tech. Phys., 12, 593 (1931).
18). K. Watanabe, E. Nakagawa, H. Yamada, H. Hisamoto and K. Suzuki, Anal. Chem., 65, 2704 (1993).
19). U. Oesch, D. Ammann and W. Simon, Clin. Chem., 32, 1448 (1986).
20). R. G. Pearson, J. Chem. Educ., 45, 643 (1968).

Right : 1). O. S. Wolfbeis and B. P. H. Schaffer, Anal. Chim. Acta, 198, 1 (1987).
2). K. Suzuki, H. Ohzora, K. Tohda, K. Miyazaki, K. Watanabe, H. Inoue and T. Shirai, Anal. Chim. Acta, 237, 155 (1990).
3). K. Suzuki, K. Tohda, Y. Tanda, H. Ohzora, S. Nishihama, H. Inoue and T. Shirai, Anal. Chem., 61, 382 (1989).
4). W. E. Morf, K. Seiler, B. Rusterholz and W. Simon, Anal. Chem., 62, 738 (1990).
5). K. Seiler, W. E. Morf, B. Rusterholz and W. Simon, Anal. Sci., 5, 57 (1990).
6). S. S. S. Tan, P. C. Hauser, N. A. Chaniotakis, G. Suter and W. Simon, Chimia, 43, 257 (1989).
7). K. Miyazaki, K. Tohda, H. Ohzora, K. Watanabe, H. Inoue and K. Suzuki, Bunseki Kagaku, 39, 717 (1990).
8). H. Oka, K. Miyazaki, K. Watanabe, K. Tohda, H. Inoue and K. Suzuki, The 6lst Ann. Cong, of Chem. Soc. of Jpn., Abst., p. 650, March, 1991.
9). S. S. S. Tan, P. C. Hauser, K. Wang, K. Fluri, K. Seiler, B. Rusterholz, G. Suter, M. Kruttli, U. E. Spichiger and W. Simon, Anal. Chim. Acta, 255, 35 (1991).
10). M. A. Arnold, Anal. Chem., 64, 1015A (1992).
11). J. Janata, Anal. Chem., 64, 196R (1992).
12). J. Janata, Anal. Chem., 64, 921A (1992).
13). D. Ammann, M. Huser, B. Krautler, B. Rusterholz, P. Schulthess. B. Lindemann, E. Halder and W. Simon, Helv. Chim. Acta, 69, 849 (1986).
14). N. A. Chaniotakis, S. B. Park and M. E. Meyerhoff, Anal. Chem., 61, 566 (1989).
15). Y. Umezawa, M. Kataoka, W. Takami, E. Kimura, T. Koike and H. Nada, Anal. Chem., 60, 2392 (1988).
16). S. A. Glazier and M. A. Arnold, Anal. Chem., 63, 754 (1991).
17). P. Kubelka and Z. Munk, Z. Tech. Phys., 12, 593 (1931).
18). K. Watanabe, E. Nakagawa, H. Yamada, H. Hisamoto and K. Suzuki, Anal. Chem., 65, 2704 (1993).
19). U. Oesch, D. Ammann and W. Simon, Clin. Chem., 32, 1448 (1986).
20). R. G. Pearson, J. Chem. Educ., 45, 643 (1968).}

Date of correction: July 04, 2006 Reason for correction: - Correction: PDF FILE Details: -

Abstract

Universitätstrasse 16, CH-8092 Zürich, Switzerland Flow-through type fiber-optic chloride ion selective optodes have been developed based on chloride adducts of lipophilic organometallic compounds, including a metal: Sn, Ge, Hg or Hf and a lipophilic anionic indicator dye of the diphenyl amine type. The pellicular-type ODS beads were coated with a lipophilic organic liquid containing the lipophilic organometallic compound as the anion-selective ionophore ligand and LAD-3 as the color changeable indicator dye. The optode system was constructed by packing these color changeable ion sensing beads in the flow-through optical cell (cell volume, 7μl) having a quartz window attached directly to the distal end of a bifurcated optical fiber. The optode based on tricyclohexyltin chloride (TCTCl) exhibited the most sensitive response to chloride ion among all the sensors using the organometallic compounds investigated. This optode could detect chloride ion in the concentration ranging from 10^-4to 1M at pH 6.5 with a 0.01M sodium phosphate buffer as the flowing solution by measuring the absorbance change in the sensing beads at 516nm. This optode showed sufficient selectivity for the determination of chloride ion in normal human serum.

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