Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Ligand Determination of a Copper Complex by Cu 2p X-Ray Photoelectron Spectroscopy
Jun KAWAISei TSUBOYAMAKazuhiko ISHIZUKazuo MIYAMURAMasahiko SABURI
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1994 Volume 10 Issue 6 Pages 853-857

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Abstract

The copper 2p X-ray photoelectron spectra (XPS) of cupric complexes, the structures of which have been well characterized, were measured. The intensity of the so-called "shake-up" satellite relative to the main line was also measured. It was found that the satellite intensity decreased as the cupric complex became covalent. It was also found using this satellite intensity that a cupric complex of (S)-3-aminohexahydroazepine (abbreviated as S-ahaz), [Cu(S-ahaz)2](BF4)2, is directly coordinated by an F atom.

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© The Japan Society for Analytical Chemistry
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