Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Electrospray Mass Spectrometric Detection of Unstable Rhenium Complexes as Reaction Intermediates of Photochemical CO2-Fixation
Hisao HORI, Osamu ISHITANI, Kazuhide KOIKE, Koji TAKEUCHI, Takashi IBUSUKI
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Keywords: Electrospray mass spectrometry, reaction intermediate, rhenium complex, triethanolamine complex
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1996 Volume 12 Issue 4 Pages 587-590

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Abstract
Reaction intermediates of CO2-photofixation using [Re(bpy)(CO)3PPh3]+(bpy=2, 2′-bipyridine) have been studied by electrospray mass spectrometry. A triethanolamine (TEOA) complex, [Re(bpy)(CO)3(TEOA)]+, was detected for the first time as a key intermediate. Electrospray mass spectrometry was found quite useful for detecting and identifying unstable photoreaction intermediates of rhenium complexes.
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© The Japan Society for Analytical Chemistry
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