Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
PROFILE CHANGES OF THE OXYGEN K X-RAY FLUORESCENCE SPECTRA OF COPPER COMPOUNDS INCLUDING HIGH Tc SUPERCONDUCTORS
MASAHIRO SAKAISHIGEMI KOHIKISEI FUKUSHIMAJUN KAWAIYOHICHI GOHSHI
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1991 Volume 7 Issue Supple Pages 1207-1208

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Abstract

Profile changes of 0K x-ray fluorescence spectra of various copper compounds are measured. Theoretical spectra are obtained by molecular orbital calculations on linear O-Cu and Cu-O-Cu model clusters. The theoretical spectra reproduce the experimental ones very well when the contribution to the x-ray transition of σ- and π-orbitals is taken into account.

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© The Japan Society for Analytical Chemistry
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