Synthesis of (±)-Methyl Tuberonate, a Potato Tuber-forming Substance, and Its Epimer

Hiromasa KIYOTA; Daisuke NAKASHIMA; Takayuki ORITANI

doi:10.1271/bbb.63.2110

Bioscience, Biotechnology, and Biochemistry

Online ISSN : 1347-6947
Print ISSN : 0916-8451

Organic Chemistry Regular Papers

Synthesis of (±)-Methyl Tuberonate, a Potato Tuber-forming Substance, and Its Epimer

Hiromasa KIYOTA, Daisuke NAKASHIMA, Takayuki ORITANI

Author information

Keywords: methyl tuberonate, methyl 12-hydroxyjasmonate, jasmonic acid, potato tuberization, total synthesis

JOURNAL FREE ACCESS

1999 Volume 63 Issue 12 Pages 2110-2117

DOI https://doi.org/10.1271/bbb.63.2110

Details

Abstract

Methyl esters of (±)-tuberonic acid and (±)-12-hydroxyjasmonic acid (trans-tuberonic acid), the aglycons of strong potato tuber-forming substances, were synthesized from norbornene via side-chain elongation and Baeyer-Villiger oxidation as key steps.

Content from these authors

This article cannot obtain the latest cited-by information.

Favorites & Alerts

Corresponding author

Register with J-STAGE for free!