Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Zinc Bismuthate Zn(BiO3)2. I. A Useful Oxidizing Agent for the Efficient Oxidation of Organic Compounds
Habib FirouzabadiIraj Mohammadpour-Baltork
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1992 Volume 65 Issue 4 Pages 1131-1134

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Abstract

Zinc bismuthate is an easily prepared and a stable compound. It could be used as an oxidant in organic solvents under aprotic or in the presence of a catalytic amount of a protic solvent. Primary and secondary saturated, allylic, and benzylic alcohols are converted to their carbonyl compounds in high yields. Mildness of the reagent is shown by the oxidation of thiols to their disulfides in excellent yields. Thioethers are also oxidized to their corresponding sulfoxides in good yields.

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© 1992 The Chemical Society of Japan
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