Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Stability and Resonance Energy of Azulenequinones and the Rule for Topological Charge Stabilization
Teruo KuriharaSumio IshikawaTetsuo Nozoe
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1992 Volume 65 Issue 4 Pages 1151-1153

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Abstract

An examination was made of the stability and formation pathways of azulenequinones produced by oxygenation in terms of Aihara’s graph theory of aromaticity and Gimarc’s TCS rule. In view of the TCS rule, the oxygen molecule in autoxidation first attacks C-1 of the azulenes, followed by the another oxygen molecule attacking at position n in 1-carbonylated azulenes to give azulenequinones.

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© 1992 The Chemical Society of Japan
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