Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Total Synthesis of Siastatin B and Its Enantiomer Using Carbohydrate as a Chiral Educt
Yoshio NishimuraWhen-mei WangToshiaki KudoShinichi Kondo
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1992 Volume 65 Issue 4 Pages 978-986

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Abstract

The enantioselective synthesis of siastatin B, an inhibitor of neuraminidase and its antipode from D-ribono-γ-lactone has stereospecifically been achieved. The total synthesis elucidated the absolute configuration of siastatin B as (3S,4S,5R,6R)-6-acetamido-4,5-dihydroxy-3-piperidinecarboxylic acid.

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© 1992 The Chemical Society of Japan
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