Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Optical Properties and Thermochromism of the Crystals of Chloranil-Hexamethyl Benzene and Fluoranil-Perylene Charge-Transfer Complexes
Masashi Tanaka
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1993 Volume 66 Issue 11 Pages 3171-3174

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Abstract

The reflection spectra of the crystal of chloranil-hexamethyl benzene and fluoranil-perylene charge-transfer complexes were measured, and the charge-transfer degrees in these complexes were estimated. Furthermore, the polarized IR absorption spectra of these crystals were measured and compared with those of the powders of the complexes and the component compounds in the KBr disks. The thermochromism of these CT complex crystals was studied by differential scanning calorimetry and the IR spectra.

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© 1993 The Chemical Society of Japan
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