1993 Volume 66 Issue 11 Pages 3171-3174
The reflection spectra of the crystal of chloranil-hexamethyl benzene and fluoranil-perylene charge-transfer complexes were measured, and the charge-transfer degrees in these complexes were estimated. Furthermore, the polarized IR absorption spectra of these crystals were measured and compared with those of the powders of the complexes and the component compounds in the KBr disks. The thermochromism of these CT complex crystals was studied by differential scanning calorimetry and the IR spectra.
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