Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Complexation Equilibria and Fluorescent Properties of Chelating Reagents Derived from Ethylene Glycol Bis(β-aminoethylether)-N,N,N′,N′-tetraacetic Acid
Akio YuchiAtsushi TanakaManabu HiraiTakashi YasuiHiroko WadaGenkichi Nakagawa
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1993 Volume 66 Issue 11 Pages 3377-3381

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Abstract

The complexation equilibria of divalent and lanthanoid metal ions with 1,2-bis(o-aminophenoxy)ethane-N,N,N′,N′-tetraacetic acid (BAPTA) and 2-[(2-amino-5-methylphenoxy)methyl]-6-methoxy-8-aminoquinoline-N,N,N′,N′-tetraacetic acid (quin2) were studied by pH titration. In lanthanoids, BAPTA shows a maximum stability for Pr3+, whereas quin2 has higher affinities for heavier ones. These trends are discussed in terms of the rigidity and donor atoms of these ligands. Intense fluorescence was observed for quin2 complexes of Group-2 and -3 elements. Among the lanthanoids, only Sc, Y, La, Gd, and Lu enhance the fluorescence at around 380 nm.

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© 1993 The Chemical Society of Japan
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