Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Synthesis and Mercurophilic Properties of Sulfur-Containing Troponoid Crown Ethers
Hitoshi TakeshitaBing Zhu YinKanji KuboAkira Mori
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1993 Volume 66 Issue 11 Pages 3451-3455

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Abstract

Condensation of 2,7-dibromotropone and 7-bromo-4-isopropyl-2-(4-tolysulfonyloxy)tropone with oligoethylene glycol bis(2-mercaptoethyl) ethers gave sulfur-containing crown ether derivatives. Among these mercurophilic derivatives, triethylene glycol bis(2-mercaptoethyl) derivatives transport and extract mercury ion excellently.

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© 1993 The Chemical Society of Japan
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