Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Addition Effect of Hydrogen Bromide on Methane Ignition behind Reflected Shock Waves
Kazuo TakahashiTadaaki InomataHiroshi Jinno
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1993 Volume 66 Issue 11 Pages 3503-3505

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Abstract

Ignition delay times were measured in a CH4–O2–HBr–Ar mixture behind reflected shock waves. Hydrogen bromide retarded methane ignition, though methyl bromide accelerated it. Model calculations showed that two different chain cycles, promotion and inhibition cycles, were formed for bromine-containing species. The inhibition cycle was predominant in the HBr addition.

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© 1993 The Chemical Society of Japan
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