1993 Volume 66 Issue 11 Pages 3503-3505
Ignition delay times were measured in a CH4–O2–HBr–Ar mixture behind reflected shock waves. Hydrogen bromide retarded methane ignition, though methyl bromide accelerated it. Model calculations showed that two different chain cycles, promotion and inhibition cycles, were formed for bromine-containing species. The inhibition cycle was predominant in the HBr addition.
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