Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Thermochromic Crystals of the CT Complex between N-Salicylidene-2-aminopyridine and 1,3,5-Trinitrobenzene
Masashi TanakaTakayuki ImaiTakehiko GotoJun-ichiro TakaMitsuhiro AkamatsuSetsuo KashinoKouichi Mogi
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1998 Volume 71 Issue 11 Pages 2561-2571

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Abstract

N-Salicylidene-2-aminopyridine (NSAP) and 1,3,5-trinitrobenzene (TNB) form two kind of crystalline (1/2) complexes, forms I and II. The thermochromism was observed in a charge transfer complex form I, but not in form II. The thermochromism of these crystals was studied based on the temperature dependence of the X-ray analysis and the IR and visible absorption spectra together with the theoretical analysis.

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© 1998 The Chemical Society of Japan
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