Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) Peroxodisulfate: A Mild and Efficient Oxidant for Cleavage of Nitrogen Double Bonds and Oxidation of Alcohols under Anhydrous Conditions
Abdol Reza HajipourIraj Mohammadpoor -BaltorkGodaraz Kianfar
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1998 Volume 71 Issue 11 Pages 2655-2659

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Abstract

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate (1), is readily prepared as an orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane and potassium peroxodisulfate. This reagent easily converts hydrazones, semicarbazones, oximes, and alcohols to the corresponding carbonyl compounds with excellent yields.

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© 1998 The Chemical Society of Japan
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