Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Facile Synthesis of α-Fluoroalkyl Sulfides under the Oxidative Desulfurization–Fluorination Conditions
Satoru FurutaManabu KuroboshiTamejiro Hiyama
Author information
JOURNALS RESTRICTED ACCESS

1998 Volume 71 Issue 11 Pages 2687-2694

Details
Abstract

Upon treatment with n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin, various organic sulfides underwent a Pummerer-type rearrangement, followed by fluorination, to give α-fluoro sulfides. The fluoro-Pummerer rearrangement, when applied to RCH(SMe)CF2SMe, gave trifluoro sulfides RCF(SMe)CF2SMe. When an HF-pyridine reagent was used as the fluorinating agent, an oxidative desulfurization–fluorination reaction occurred depending on the structure of the substrates.

Information related to the author

This article cannot obtain the latest cited-by information.

© 1998 The Chemical Society of Japan
Previous article Next article
feedback
Top