2002 Volume 75 Issue 11 Pages 2469-2470
Syntheses of a new planar terdentate ligand, 6-(3,5-diphenyl-2-pyrrolyl)-2,2′-bipyridine (L1H) and its ruthenium(II) complex ([Ru(L1)2]) are reported. The X-ray structure of [Ru(L1)2] showed the distorted octahedral Ru(II) center similar to the structures of terpyridine complexes. The cyclic voltammograms revealed that [Ru(L1)2] was more easily oxidized than [Ru(terpy)2]2+ by 1.10 V.
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