Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Radiolytic Degradation of Chlorinated Hydrocarbons in Water
Xing-Zheng WuTakeshi YamamotoMasanori Hatashita
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2002 Volume 75 Issue 11 Pages 2527-2532


Radiolytic degradation of chlorinated hydrocarbons (chloroform, trichloroethylene, and tetrachloroethylene) in water was carried out. Water solutions of the chlorinated hydrocarbons with different concentrations were irradiated with γ rays. Concentrations of methane, ethane, CO, CO2, H2, and O2 after the irradiation were determined by gas chromatography. Concentration of chloride ion in the irradiated sample was determined by ion chromatography. Experimental results show that radiolytic degradation of the chlorinated hydrocarbon increased with the radiation dose. Methane, ethane, CO2, H2, and Cl concentrations increased with the radiation dose and the sample concentration. On the other hand, O2 concentration decreased with the radiation dose and the sample concentration. When sample concentration was high, dissolved oxygen might be not enough for converting most of the C atoms in the sample into CO2. This resulted in a low decomposition ratio. Addition of H2O2 as an oxygen resource could increase the decomposition ratio greatly. Furthermore, gas chromatography-mass spectroscopy was applied to identify some intermediates of the radiolytic dehalogenation. Radiolytic degradation mechanisms are also discussed.

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© 2002 The Chemical Society of Japan
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