2003 Volume 76 Issue 11 Pages 2151-2152
The quenching of the photoluminescence of [Pt(binap)2] by oxygen has been studied. Generation of singlet oxygen was confirmed by NIR spectroscopy. The usefulness of the Pt complex as a photosensitizer was established using a singlet oxygen scavenger, 1,3-diphenylisobenzofuran (DBF). The mechanism for the generation of singlet oxygen is discussed.
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