Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Synthesis, Solubility, and Reaction of Long Alkyl-Chained Hypervalent Iodine Benzyne Precursors
Takayoshi AbeTeizo YamajiTsugio Kitamura
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2003 Volume 76 Issue 11 Pages 2175-2178

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Abstract

Long-chained hypervalent iodine benzyne precursors bearing ethyl, butyl, hexyl, octyl, decyl, dodecyl, and tetradecyl groups were synthesized, respectively. As the alkyl chain of the benzyne precursors is lengthened, the solubility in nonpolar organic solvents and the yield of the benzyne adduct with furan gradually increases.

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© 2003 The Chemical Society of Japan
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