Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Analytical and Inorganic
Thermal and Photo-Responsibility of Axial Semi-Coordination Bonds in a Copper(II) Complex
Takashiro AkitsuYasuaki Einaga
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2004 Volume 77 Issue 4 Pages 763-764

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Abstract

The thermal and photo-responsibility of the axial semi-coordination Cu–O bonds in [Cu(en)2](ClO4)2 (1) (en = ethylenediamine) have been investigated. We discovered a new photoresponsive behavior that was attributed to photo-induced ClO4 cleavage accompanied by compression of the Cu–O bonds using the structural degree of freedom of the semi-coordination bonds.

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© 2004 The Chemical Society of Japan
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