Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Articles
Thermal Isomerization at a C=N Double Bond: How Does the Mechanism Vary with the Substituent?
Hiroshi YamatakaSalai Cheettu AmmalTsutomu AsanoYasushi Ohga
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2005 Volume 78 Issue 10 Pages 1851-1855

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Abstract

Thermal isomerizations at the C=N double bonds in R1R2C=NC6H4X proceed via an inversion mechanism, in which the C=NC6H4X bond angle is near 180° at the transition state (TS). Available experimental data on the reactions of (CF3)2C=NC6H4X and YC6H4CH=NC6H4X have suggested that the reaction mechanism changes with substituent X. In the present study, HF, B3LYP, and MP2 computations were carried out to analyze the modes of mechanistic change with the substituent for the reactions of (CF3)2C=NC6H4X, YC6H4CH=NC6H4X, and other systems. There are two possible pathways within the inversion mechanistic framework: a planar pathway with the R1R2C=N double-bond plane and the aromatic ring being coplanar at the TS and a perpendicular one with the two planes being perpendicular to each other at the TS. It was found that the mechanistic change is not due to a change in the relative importance of two independent and competitive reaction pathways, but arises from a change of the character of a single TS from planar to perpendicular geometry when the substituent becomes more electron-withdrawing.

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© 2005 The Chemical Society of Japan
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