Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
BCSJ Award Article
Facile Synthesis of Aryl- and Alkyl-bis(trifluoromethylsulfonyl)methanes
Aiko HasegawaTakuo IshikawaKazuaki IshiharaHisashi Yamamoto
Author information
JOURNALS RESTRICTED ACCESS

2005 Volume 78 Issue 8 Pages 1401-1410

Details
Abstract

Various arylbis(trifluoromethylsulfonyl)methanes (1) have been synthesized by reacting the corresponding benzylic halides with sodium trifluoromethanesulfinate and then with triflic anhydride. In addition, when the aryl group of 1 is a pentafluorophenyl group, the nucleophilic para-substitution of the aryl group with alkyllithiums and sodium alkoxides occurs. This reaction is useful for the design of new Brønsted acids.

Information related to the author

This article cannot obtain the latest cited-by information.

© 2005 The Chemical Society of Japan
Previous article Next article
feedback
Top