Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
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Conversion of 2-Aminoethanethiolate (aet) to 2-Benzoylaminoethanethiolate (L) in a S-Bridged Diruthenium(II) Complex Composed of Two cis-[Ru(bpy)2] Units. Crystal Structures of ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-Haet)2]4+ and ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-L)2]2+
Noriyuki MatsuuraTatsuya KawamotoTakumi Konno
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2006 Volume 79 Issue 2 Pages 297-299

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Abstract

A diruthenium(II) complex, ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-L)2]2+ (ΔΔ/ΛΛ-[2]2+), in which two cis-[Ru(bpy)2]2+ units are bridged by two S atoms from two 2-benzoylaminoethanethiolate (L) ligands, was synthesized by the reaction of ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-Haet)2]4+ (aet = 2-aminoethanethiolate; ΔΔ/ΛΛ-[1]4+) with benzoyl chloride in the presence of a base. The molecular structure and electrochemical properties of ΔΔ/ΛΛ-[2]2+ were discussed in comparison with those of ΔΔ/ΛΛ-[1]4+.

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© 2006 The Chemical Society of Japan
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