Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
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Preparation and Properties of Mg/Al Layered Double Hydroxide–Oleate and –Stearate Intercalation Compounds
Kazuya InomataMakoto Ogawa
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2006 Volume 79 Issue 2 Pages 336-342

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Abstract

Mg/Al layered double hydroxide–oleate and –stearate intercalation compounds were successfully synthesized by the reconstruction method under hydrothermal conditions from calcined hydrotalcite. The intercalation compounds were characterized by the high structural regularity as evidenced by the sharp and intense X-ray diffraction peaks. The oleate intercalated layered double hydroxide exhibits unique physicochemical properties such as a reversible thermoresponsive change in the basal spacing and swelling in organic solvents such as n-alkanes.

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© 2006 The Chemical Society of Japan
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