Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
 
Synthesis and Structure of a Kinetically Stabilized Stannanethione
Tomoyuki TajimaTakahiro SasamoriNobuhiro TakedaNorihiro Tokitoh
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2007 Volume 80 Issue 6 Pages 1202-1204

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Abstract

The X-ray crystallographic analysis of a stable stannanethione, Bbt(Titp)Sn=S, reveals that the tin–sulfur bond distance [2.221(3) Å] is ca. 10% shorter than the normal tin–sulfur single bonds and the tin atom of the stannanethione has a trigonal planar geometry, as do as the carbonyl carbon atoms.

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© 2007 The Chemical Society of Japan
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