Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
 
π-Conjugated Polymers, (Th(R)–CH=CH–Th(R))n (Th(R) = 3-Alkylthiophene-2,5-diyl; R = Octyl, Decyl, and Dodecyl): Preparation of Dibromo Monomers and the Polymers
Takakazu YamamotoAkira KumagaiHisashi KokuboYoshiyuki Nakamura
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JOURNALS OPEN ACCESS

2011 Volume 84 Issue 11 Pages 1291-1293

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Abstract

π-Conjugated polymers, (Th(R)–CH=CH–Th(R))n (Th(R) = 3-alkylthiophene-2,5-diyl; R = octyl, decyl, and dodecyl), and their dibromo monomers have been prepared. The polymers show a tendency to self-assemble in solutions and in the solid state. X-ray diffraction data suggest that the polymers assume an interdigitation packing in the solid state.

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© 2011 The Chemical Society of Japan
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