2011 Volume 84 Issue 11 Pages 1291-1293
π-Conjugated polymers, (Th(R)–CH=CH–Th(R))n (Th(R) = 3-alkylthiophene-2,5-diyl; R = octyl, decyl, and dodecyl), and their dibromo monomers have been prepared. The polymers show a tendency to self-assemble in solutions and in the solid state. X-ray diffraction data suggest that the polymers assume an interdigitation packing in the solid state.
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